Beilstein J. Org. Chem.2017,13, 1728–1734, doi:10.3762/bjoc.13.167
, entries 1–5), although the ee in products 2b–f remained rather high (>90%). Notably, this aliphatic chain-lengtheffect has been studied in other systems with similar results [53].
The introduction of an aromatic ring (either unsubstituted or para-substituted) in the substrate resulted in diminished
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Graphical Abstract
Scheme 1:
Enantioselective enzymatic hydrolysis of racemic β3-amino ester rac-1a using CALB in solution [52] (top...
Beilstein J. Org. Chem.2016,12, 1788–1797, doi:10.3762/bjoc.12.169
; benzodithiophene; π-bridge; chainlengtheffect; organic solar cell; Introduction
Solution-processed organic solar cells (OSCs) are considered to be one of the most promising renewable energy technologies because of the advantages of low cost, lightweight, flexibility, and great potentials in large-scale
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Graphical Abstract
Scheme 1:
Synthetic route to compounds 1–4 with BDT core. Reagents and conditions: i) [Pd2(dba)3]·CHCl3, HP(t-...